Class 12th Chemistry Electrochemistry NCERT Notes CBSE 2023
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Electrochemistry Class 12 Notes

Electrochemistry Class 12 Notes

Class 12 Chemistry Chapter 3 Electrochemistry Notes – PDF Download

Chapter 3 Electrochemistry Notes

NCERT notes provide step-by-step explanations for all questions and solving them will help maximize student scores. After practicing the questions of electrochemistry, students will become proficient in areas such as electrochemical cells, galvanic cells, and electrolytic cells. Practicing electrochemistry-related questions will help students score well in CBSE Grade 12 Chemistry exams and also help them pass competitive exams like JEE, NEET, etc. Measure electrode potential, Nernst equation, primary and secondary batteries, and more. Vidyakul offers a set of over 400 practice questions for all the sub topics covered in Chapter 3. All questions in the text must be practiced without a high score. Scroll down to see NCERT notes for Grade 12 Chemistry Chapter 3.


CBSE CLASS 12th CHEMISTRY 3 NOTES

Points to Remember

Below is the list of important topics included in Class 12 Chemistry Chapter 3 Electrochemistry.

Sr. No

Name of the Topic

Description

1

Electrochemical Cells

2

Galvanic Cells

3

Electrode Potential and Standard Electrode Potential

4

Nernst Equation

5

Relationship between Electrode Potential, Gibb’s Free Energy and Equilibrium Constant

6

Electrolytic and Metallic Conduction

7

Conductance in Electrolytic Solutions

8

Kohlrausch’s Law and Its Application

9

Electrolytic Cells and Electrolysis

10

Batteries

 

11

Fuel Cells

 

12

Corrosion and Its Prevention

 

 

 

 

 

 

Points to Remember

Students can find the important points to remember from NCERT Class 12 Chemistry Chapter 3, as mentioned below. Going through the points before final exams helps students to have a quick revision of Chapter 3 Chemistry.

  • Electrochemical Cell: A device that converts chemical energy into electrical energy.

  • Anode: In electrochemical cells, the anode is the electrode at which oxidation takes place. It is the negative terminal.

  • Cathode: In electrochemical cells, the cathode is the electrode at which reduction takes place. It is the positive terminal.

  • EMF of the cell or Ecell = Ecathode −Eanode .

  • Thermodynamic Efficiency of Cell: It is the ratio of Gibb’s energy change to the enthalpy change of the cell reaction η = ΔG/ΔH.

  • Electrochemical Series: Arrangement of various elements and electrode reactions in the increasing order of their reduction potentials.

  • Electrolyte: A substance that dissociates in solution to produce ions and hence conducts electricity in a dissolved state or molten state.

  • Molar Conductivity: Conductance of a solution containing one mole of the electrolyte, placed between two parallel electrodes one cm apart.



Topics and Sub-Topics

Below is the list of important topics included in Class 12 Chemistry Chapter 3 Electrochemistry.

Sr. No

Name of the Topic

Description

1

Electrochemical Cells

A device that generates a potential difference between electrodes by chemical reactions is called an electrochemical cell. It comprises two electron conductors which are separated by an ionic conductor and are linked by an electron conductor. The two metallic electrodes are dipped in the electrolytic solution. The important component of this cell is an ionic conductor.

2

Galvanic Cells

  • Galvanic cell – In a galvanic cell, spontaneous redox reaction, the chemical energy is converted into electrical energy. It is also called voltaic cell or Daniel cell.

3

Electrode Potential and Standard Electrode Potential

4

Nernst Equation

5

Relationship between Electrode Potential, Gibb’s Free Energy and Equilibrium Constant

6

Electrolytic and Metallic Conduction

7

Conductance in Electrolytic Solutions

8

Kohlrausch’s Law and Its Application

9

Electrolytic Cells and Electrolysis

  • Electrolytic cell – In an electrolytic cell, the nonspontaneous redox reaction is carried out by electrical energy.

 

10

Batteries

11

Fuel Cells

12

Corrosion and Its Prevention

 


 


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Few Important Questions

  • What is a ‘Galvanic cell’?

Galvanic cell is an electrochemical cell in which an electric current is generated from spontaneous oxidation-reduction reactions.

  • What is ‘EMF’?

Electromotive force is equal to the terminal potential difference when no current flows.

  • What is ‘Reduction potential’?

Reduction potential is the a tendency of a chemical species to be reduced by gaining an electron.


Practice Questions

  1. Define and distinguish between molar conductivity and conductivity.

  2. How much charge is required to reduce 1 mol of Al3+ to Al?

  3. How much electricity is necessary for the oxidation of 1 mol of H2O to O2 in a coulomb?

  4. Find the cell constant of 0.001M KCl solution with the following details:

T = 208 K, conductivity = 0.146 × 10–3 S cm–1, R = 1500 Ω

  1. Calculate the molar conductivity for the following:

Conductivity = 0.0248 S cm–1, 0.20 M solution of KCl solution, Temperature = 298 K

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